GHS Precautionary Statement List

GHS

GHS Precautionary Statement List

Little Pro on 2016-01-06

GHS precautionary statement means a standard phrase that describes measures to minimize or prevent adverse effects of a chemical. Each precautionary statement is designated a code, starting with the letter P and followed by 3 digits.

P1xx: general precautionary statement;
P2xx: prevention precautionary statement;
P3xx: response precautionary statement;
P4xx: storage precautionary statement;
P5xx: disposal precautionary statement;

It shall be noted that the P code is used for reference purpose only. It is the actual phrase which should appear on labels and safety data sheets.

List of GHS Precautionary Statements and P Codes

General Precautionary Statements
P101	If medical advice is needed, have product container or label at hand.
P102	Keep out of reach of children.
P103	Read label before use
Prevention Precautionary Statements
P201	Obtain special instructions before use.
P202	Do not handle until all safety precautions have been read and understood.
P210	Keep away from heat, hot surface, sparks, open flames and other ignition sources. - No smoking.
P211	Do not spray on an open flame or other ignition source.
P212	Avoid heating under confinement or reduction of the desensitized agent.
P220	Keep away from clothing and other combustible materials.
P221	Take any precaution to avoid mixing with combustibles/...
P222	Do not allow contact with air.
P223	Do not allow contact with water.
P230	Keep wetted with ...
P231	Handle under inert gas.
P232	Protect from moisture.
P233	Keep container tightly closed.
P234	Keep only in original container.
P235	Keep cool.
P240	Ground/bond container and receiving equipment.
P241	Use explosion-proof [electrical/ventilating/lighting/.../] equipment.
P242	Use only non-sparking tools.
P243	Take precautionary measures against static discharge.
P244	Keep valves and fittings free from oil and grease.
P250	Do not subject to grinding/shock/friction/...
P251	Do not pierce or burn, even after use.
P260	Do not breathe dust/fume/gas/mist/vapors/spray.
P261	Avoid breathing dust/fume/gas/mist/vapors/spray.
P262	Do not get in eyes, on skin, or on clothing.
P263	Avoid contact during pregnancy/while nursing.
P264	Wash ... thoroughly after handling.
P270	Do not eat, drink or smoke when using this product.
P271	Use only outdoors or in a well-ventilated area.
P272	Contaminated work clothing should not be allowed out of the workplace.
P273	Avoid release to the environment.
P280	Wear protective gloves/protective clothing/eye protection/face protection.
P281	Use personal protective equipment as required.
P282	Wear cold insulating gloves/face shield/eye protection.
P283	Wear fire resistant or flame retardant clothing.
P284	[In case of inadequate ventilation] Wear respiratory protection.
P285	In case of inadequate ventilation wear respiratory protection.
P231+P232	Handle under inert gas/... Protect from moisture.
P235+P410	Keep cool. Protect from sunlight.
Response Precautionary Statements
P301	IF SWALLOWED:
P302	IF ON SKIN:
P303	IF ON SKIN (or hair):
P304	IF INHALED:
P305	IF IN EYES:
P306	IF ON CLOTHING:
P307	IF exposed:
P308	IF exposed or concerned:
P309	IF exposed or if you feel unwell
P310	Immediately call a POISON CENTER or doctor/physician.
P311	Call a POISON CENTER or doctor/...
P312	Call a POISON CENTER or doctor/... if you feel unwell.
P313	Get medical advice/attention.
P314	Get medical advice/attention if you feel unwell.
P315	Get immediate medical advice/attention.
P320	Specific treatment is urgent (see ... on this label).
P321	Specific treatment (see ... on this label).
P322	Specific measures (see ...on this label).
P330	Rinse mouth.
P331	Do NOT induce vomiting.
P332	IF SKIN irritation occurs:
P333	If skin irritation or rash occurs:
P334	Immerse in cool water [or wrap in wet bandages].
P335	Brush off loose particles from skin.
P336	Thaw frosted parts with lukewarm water. Do not rub affected area.
P337	If eye irritation persists:
P338	Remove contact lenses, if present and easy to do. Continue rinsing.
P340	Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P341	If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing.
P342	If experiencing respiratory symptoms:
P350	Gently wash with plenty of soap and water.
P351	Rinse cautiously with water for several minutes.
P352	Wash with plenty of water/...
P353	Rinse skin with water [or shower].
P360	Rinse immediately contaminated clothing and skin with plenty of water before removing clothes.
P361	Take off immediately all contaminated clothing.
P362	Take off contaminated clothing.
P363	Wash contaminated clothing before reuse.
P364	And wash it before reuse.[Added in 2015 version]
P370	In case of fire:
P371	In case of major fire and large quantities:
P372	Explosion risk.
P373	DO NOT fight fire when fire reaches explosives.
P374	Fight fire with normal precautions from a reasonable distance.
P376	Stop leak if safe to do so.
P377	Leaking gas fire: Do not extinguish, unless leak can be stopped safely.
P378	Use ... to extinguish.
P380	Evacuate area.
P381	In case of leakage, eliminate all ignition sources.
P390	Absorb spillage to prevent material damage.
P391	Collect spillage.
P301+P310	IF SWALLOWED: Immediately call a POISON CENTER/doctor/...
P301+P312	IF SWALLOWED: call a POISON CENTER/doctor/... IF you feel unwell.
P301+P330+P331	IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P302+P334	IF ON SKIN: Immerse in cool water [or wrap in wet bandages].
P302+P335+P334	Brush off loose particles from skin. Immerse in cool water [or wrap in wet bandages].
P302+P350	IF ON SKIN: Gently wash with plenty of soap and water.
P302+P352	IF ON SKIN: wash with plenty of water.
P303+P361+P353	IF ON SKIN (or hair): Take off Immediately all contaminated clothing. Rinse SKIN with water [or shower].
P304+P312	IF INHALED: Call a POISON CENTER/doctor/... if you feel unwell.
P304+P340	IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P304+P341	IF INHALED: If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305+P351+P338	IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do - continue rinsing.
P306+P360	IF ON CLOTHING: Rinse Immediately contaminated CLOTHING and SKIN with plenty of water before removing clothes.
P307+P311	IF exposed: call a POISON CENTER or doctor/physician.
P308+P311	IF exposed or concerned: Call a POISON CENTER/doctor/...
P308+P313	IF exposed or concerned: Get medical advice/attention.
P309+P311	IF exposed or if you feel unwell: call a POISON CENTER or doctor/physician.
P332+P313	IF SKIN irritation occurs: Get medical advice/attention.
P333+P313	IF SKIN irritation or rash occurs: Get medical advice/attention.
P335+P334	Brush off loose particles from skin. Immerse in cool water/wrap in wet bandages.
P337+P313	IF eye irritation persists: Get medical advice/attention.
P342+P311	IF experiencing respiratory symptoms: Call a POISON CENTER/doctor/...
P361+P364	Take off immediately all contaminated clothing and wash it before reuse.
P362+P364	Take off contaminated clothing and wash it before reuse.
P370+P376	in case of fire: Stop leak if safe to do so.
P370+P378	In case of fire: Use ... to extinguish.
P370+P380	In case of fire: Evacuate area.
P370+P380+P375	In case of fire: Evacuate area. Fight fire remotely due to the risk of explosion.
P371+P380+P375	In case of major fire and large quantities: Evacuate area. Fight fire remotely due to the risk of explosion.
Storage Precautionary Statements
P401	Store in accordance with ...
P402	Store in a dry place.
P403	Store in a well-ventilated place.
P404	Store in a closed container.
P405	Store locked up.
P406	Store in corrosive resistant/... container with a resistant inner liner.
P407	Maintain air gap between stacks or pallets.
P410	Protect from sunlight.
P411	Store at temperatures not exceeding ... °C/...°F.
P412	Do not expose to temperatures exceeding 50 °C/ 122 °F.
P413	Store bulk masses greater than ... kg/...lbs at temperatures not exceeding ... °C/...°F.
P420	Store separately.
P422	Store contents under ...
P402+P404	Store in a dry place. Store in a closed container.
P403+P233	Store in a well-ventilated place. Keep container tightly closed.
P403+P235	Store in a well-ventilated place. Keep cool.
P410+P403	Protect from sunlight. Store in a well-ventilated place.
P410+P412	Protect from sunlight. Do not expose to temperatures exceeding 50 °C/122°F.
P411+P235	Store at temperatures not exceeding ... °C/...°F. Keep cool.
Disposal Precautionary Statements
P501	Dispose of contents/container to ...
P502	Refer to manufacturer or supplier for information on recovery or recycling

How to Determine GHS Precautionary Statements for A Chemical

You have to determine the hazard class and hazard category of a chemical first. Once the classification of a chemical has been determined, signal word, hazard pictograms, hazard statements and precautionary statements will be assigned (see example below for flammable liquids).

GHS Precautionary Statement List

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